Si-TCP synthesized from "Mg-free" reagents employed as calcium phosphate cement
The influence of silicon doping on calcium phosphate cement were explored in this work. α-TCP and Si-α-TCP were prepared by solid state reaction employing "Mg-free" CaHPO4, CaCO3 and CaSiO3 as precursors. It was possible to obtain TCP powders with low contents of β phase as contaminant. Cement liquid phase was an aqueous solution containing 2.5 wt. (%) of Na2HPO4 and 1.5 wt. (%) of citric acid. The liquid-to-powder ratio was 0.6 mL.g-1. Chemical, physical and mechanical properties of the cement samples were determined by means of XRD, FTIR, XRF, compressive strength and SEM. The calcium phosphate cements obtained achieved satisfactory properties; however, Si-α-TCP presented a decrease on the rate of setting reaction.
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| Main Authors: | , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
ABM, ABC, ABPol
2012
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| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392012000400014 |
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