Adsorption of ions onto treated natural zeolite
This work presents studies of modification of a natural zeolite by activation with Na+ cations and functionalisation with Ba+2 and/or Cu2+ ions (FZ). The zeolite was characterized, modified and applied in adsorption studies of sulphate and isopropilxanthate ions as flocculated and powdered forms. The reuse of SO4Ba-FZ was investigated by adsorption-removal of either Ba2+ or sulphate ions in stages. Equilibrium data showed that the FZ, flocculated or as powder, provide considerable removal of sulphate ions (q mLangmuir: 1.15 and 1.35 meq.g-1, respectively) and isopropilxanthate (q mLangmuir: 0.35 and 0.93 meq.g-1, respectively). The reuse of the SO4-FZ, either powdered or flocculated also uptake significant amount of Ba2+ or sulphate ions (q mLangmuir: 1.15 meq.g-1), providing a new alternative for the exhausted adsorbent. Thus the activated and functionalised zeolites create new options on the materials engineering area with applications in environmental applied adsorption processes.
| Main Authors: | , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
ABM, ABC, ABPol
2007
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| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400014 |
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