ONE-POT SYNTHESIS OF ISOBENZOFURAN-1(3H)-ONES USING SULFURIC ACID IMMOBILIZED ON SILICA UNDER SOLVENT-FREE CONDITIONS AND SURVEY OF THIRD-ORDER NONLINEAR OPTICAL PROPERTIES
Solvent-free synthesis of isobenzofuran-1(3H)-ones have been described via reaction of phthalaldehydic acid (2-carboxybenzaldehyde) with methylaryl or cyclic ketones using sulfuric acid immobilized on silica (H2SO4-SiO2) in excellent yields (70-88%). The catalyst can be recovered by simple filtration and reused. Also, some of these compounds has been studied the third-order nonlinear optical properties by laser Gaussian z-scan techniques.
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| Main Authors: | , , , |
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| Format: | Digital revista |
| Language: | English |
| Published: |
Sociedad Chilena de Química
2015
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| Online Access: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000100011 |
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