Synthesis and characterization of conducting composites of polyaniline and carbon black with high thermal stability

In this work, a detailed chemical route to prepare thermally stable polyaniline (PANI)/carbon black (CB) composites is described. The syntheses were performed by chemical polymerization of aniline over CB particles, using different PANI/CB mass ratios. The thermal and electrical properties were characterized. Composites with mass ratio up to 65:35 (PANI:CB) showed excellent thermal stability maintaining their conducting properties when thermally treated at 230 °C for two hours, which is adequate to process these materials. Moreover, the results showed an important reduction in the surface area of the composites which have a good relationship with the improvement of the rheological properties in melt processing.

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Bibliographic Details
Main Authors: Simões,Fabio R., Bulhões,Luís O. S., Pereira,Ernesto C.
Format: Digital revista
Language:English
Published: Associação Brasileira de Polímeros 2009
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282009000100013
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