Spectroscopic investigations of iron(II) and iron(III) oxalates

In an attempt to contribute to a better characterization of FeII and FeIII oxalate complexes, an investigation of their vibrational (infrared and Raman) and 57Fe-Mössbauer spectra was performed. It is shown that the two polymorphs, α and β, of FeC2O4•2H2O cannot be accurately differentiated with any of these spectroscopic methods, demonstrating the high structural similarity of these two crystalline forms. Partially deuterated samples of β-FeC2O4•2H2O were also investigated to improve the vibrational-spectroscopic analysis. In the case of Fe2(C2O4)3•4H2O, a structural model, derived from results of combined vibrational and Mössbauer data, could be proposed. The 298 K Mössbauer spectrum for this complex is discussed in detail for the first time.

Bibliographic Details

Main Authors:	D'Antonio,Maria C., Wladimirsky,Alejandra, Palacios,Daniel, Coggiolaa,Liliana, González-Baró,Ana C., Baran,Enrique J., Mercader,Roberto C.
Format:	Digital revista
Language:	English
Published:	Sociedade Brasileira de Química 2009
Online Access:	http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000300006
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