Hetero Diels-Alder adduct formation between nitrosobenzene and tetra-methyl purpurogallin and its retro-Diels-Alder reaction

An efficient synthesis of a Diels-Alder adduct between purpurogallin tetramethyl ether (TMPG) and nitrosobenzene (NOB) is reported. The thermal decomposition kinetics of the adduct, which follows a retro-Diels-Alder mechanism, was studied using ¹H-NMR spectroscopy.

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Bibliographic Details
Main Authors: Gamenara,Daniela, Días,Eduardo, Tancred,Néstor, Heinzen,Horacio, Moyna,Patrick, Forbes,Eric J.
Format: Digital revista
Language:English
Published: Sociedade Brasileira de Química 2001
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000400008
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