Reações de oxidação de derivados de cis-octalinas promovidas por trinitrato de tálio (TTN)
The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro-4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalen-1-ol with TTN in trimethylorthoformate (TMOF).
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Digital revista |
| Language: | Portuguese |
| Published: |
Sociedade Brasileira de Química
2008
|
| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400014 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|