Synthesis of tetrazole-fused glycosides by a tandem fragmentation- cyclization reaction
The fragmentation of anomeric alkoxyl radicals (ARF) and the subsequent intramolecular cyclization promoted by hypervalent iodine reagents provide an excellent method for the synthesis of tetrazolo-sugars. This new reaction offers additional advantages for the synthesis of these compounds, including the ready availability of the starting materials, experimental simplicity, mild conditions, and good yields.
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| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | artículo biblioteca |
| Published: |
American Chemical Society
2012-06-12
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| Subjects: | Synthesis, Tetrazole, Glycosides, Cyclization reaction, |
| Online Access: | http://hdl.handle.net/10261/199392 |
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