Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes
The anodic voltammetric behavior of 4-Nitrophenol on a Boron-doped diamond electrode in aqueous solution has been studied using square wave voltammetry. After optimization of the experimental conditions, that model molecule was analyzed in pure water solutions using a Britton-Robinson buffer with pH 6.0 as the supporting electrolyte. Oxidation occurs at 1.0 V vs. Ag/AgCl in an irreversible two-electron process controlled by adsorption of the species. The detection limit (DL) obtained was 2.8 mug L-1. This result was comparable to that obtained from reduction of the molecule at -0.8 V vs. Ag/AgCl under the same experimental conditions (DL = 4.2 mug L-1). Both DL values are within the limits required by the legislation for drinking water (30 mug L-1). The combination of square wave voltammetry and diamond electrodes has proved to be an interesting and desirable alternative for the analytical determination of organic molecules.
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Sociedade Brasileira de Química
2003
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oai:scielo:S0103-505320030004000072003-09-16Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodesPedrosa,Valber de A.Codognoto,LúciaAvaca,Luis Alberto 4-nitrophenol square wave voltammetry diamond electrodes The anodic voltammetric behavior of 4-Nitrophenol on a Boron-doped diamond electrode in aqueous solution has been studied using square wave voltammetry. After optimization of the experimental conditions, that model molecule was analyzed in pure water solutions using a Britton-Robinson buffer with pH 6.0 as the supporting electrolyte. Oxidation occurs at 1.0 V vs. Ag/AgCl in an irreversible two-electron process controlled by adsorption of the species. The detection limit (DL) obtained was 2.8 mug L-1. This result was comparable to that obtained from reduction of the molecule at -0.8 V vs. Ag/AgCl under the same experimental conditions (DL = 4.2 mug L-1). Both DL values are within the limits required by the legislation for drinking water (30 mug L-1). The combination of square wave voltammetry and diamond electrodes has proved to be an interesting and desirable alternative for the analytical determination of organic molecules.info:eu-repo/semantics/openAccessSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society v.14 n.4 20032003-08-01info:eu-repo/semantics/articletext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400007en10.1590/S0103-50532003000400007 |
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Pedrosa,Valber de A. Codognoto,Lúcia Avaca,Luis Alberto |
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Pedrosa,Valber de A. Codognoto,Lúcia Avaca,Luis Alberto Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
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Pedrosa,Valber de A. Codognoto,Lúcia Avaca,Luis Alberto |
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Pedrosa,Valber de A. |
title |
Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
title_short |
Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
title_full |
Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
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Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
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Electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
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electroanalytical determination of 4-nitrophenol by square wave voltammetry on diamond electrodes |
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The anodic voltammetric behavior of 4-Nitrophenol on a Boron-doped diamond electrode in aqueous solution has been studied using square wave voltammetry. After optimization of the experimental conditions, that model molecule was analyzed in pure water solutions using a Britton-Robinson buffer with pH 6.0 as the supporting electrolyte. Oxidation occurs at 1.0 V vs. Ag/AgCl in an irreversible two-electron process controlled by adsorption of the species. The detection limit (DL) obtained was 2.8 mug L-1. This result was comparable to that obtained from reduction of the molecule at -0.8 V vs. Ag/AgCl under the same experimental conditions (DL = 4.2 mug L-1). Both DL values are within the limits required by the legislation for drinking water (30 mug L-1). The combination of square wave voltammetry and diamond electrodes has proved to be an interesting and desirable alternative for the analytical determination of organic molecules. |
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Sociedade Brasileira de Química |
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2003 |
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http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000400007 |
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AT pedrosavalberdea electroanalyticaldeterminationof4nitrophenolbysquarewavevoltammetryondiamondelectrodes AT codognotolucia electroanalyticaldeterminationof4nitrophenolbysquarewavevoltammetryondiamondelectrodes AT avacaluisalberto electroanalyticaldeterminationof4nitrophenolbysquarewavevoltammetryondiamondelectrodes |
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